Geochemical Processes Controlling Migration of Tank Wastes in Hanford’s Vadose Zone

نویسندگان

  • John M. Zachara
  • Jeff Serne
  • Mark Freshley
  • Fred Mann
  • Frank Anderson
  • Marcus Wood
  • Tom Jones
چکیده

985 The Hanford Site in south-central Washington State produced plutonium for the USDOE weapons program from 1943 to 1989. Plutonium (Pu) production involved the fi ssion of uranium fuels using nine nuclear reactors along the Columbia River, followed by the extraction and concentration of trace product Pu through chemically intensive processing regimes performed in the central portion of the site. Three primary processing schemes were used during the lifetime of Hanford (bismuth phosphate [1944–1956], redox [1952–1967], and plutonium and uranium recovery by extraction [PUREX; 1956–1972, 1983–1989]), as improvements were sought to reduce waste volumes, allow U separation for reuse, and enhance Pu recovery effi ciency. Large volumes of radioactive waste were generated by processing, and the waste chemistry and composition varied markedly between the three processing schemes. The most concentrated and radioactive of these wastes were sent to 177 underground waste storage tanks. The fi rst of these were single-shell tanks. The 149 large, single-shell, steel/concrete underground storage tanks ranged in volume from 209,000 L (55,000 gal) to >3.8 million L (1.0 million gal) (See Fig. 1, the S-SX tank farm under construction) with a total storage volume of 357 Geochemical Processes Controlling Migration of Tank Wastes in Hanford’s Vadose Zone

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تاریخ انتشار 2007